## Abstract For each of HNO, FNO, LiNO, LiON and HF~2~^−^, __ab initio__ valence‐bond wave functions are reported for the four‐electron three‐center bonding unit which involves one of the following sets of atomic orbitals: (a) N__X__ σ‐bond (__X__ = H, For Li) and oxygen 2__p__π′; (b) LiO σ‐bond an
Multicenter bonding and the structure of electron-rich molecules. Model of three-center four-electron bonding reconsidered
✍ Scribed by Robert Ponec; Gleb Yuzhakov; David L. Cooper
- Publisher
- Springer
- Year
- 2004
- Tongue
- English
- Weight
- 524 KB
- Volume
- 112
- Category
- Article
- ISSN
- 1432-2234
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract Hypervalent bond (three center‐four electron bond: 3c‐4e) is the central feature of the structure and reactivity of hypervalent compounds. The SSS bond of thiathiophthene, the so‐called no‐bond resonance compound, is realized as one of the examples of 3c‐4e bond centered at the sulfur
## Abstract In this paper, a review is presented of the abundant literature on the two‐center three‐electron (2c‐3e) bonding, which plays a crucial role in electron transfer and radical chemistry. Important questions regarding this peculiar type of interaction are (1) Is a three‐electron bonded com