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Multi-frequency, high-field EPR as a powerful tool to accurately determine zero-field splitting in high-spin transition metal coordination complexes

✍ Scribed by J. Krzystek; Andrew Ozarowski; Joshua Telser


Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
508 KB
Volume
250
Category
Article
ISSN
0010-8545

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✦ Synopsis


Electron paramagnetic resonance at multiple, high frequencies (95-700 GHz) and at correspondingly high magnetic fields (up to 25 T), known as HFEPR, is a relatively new technique. There have been an increasing number of applications of HFEPR, such as in organic radical chemistry and in materials science. The focus of this review, however, is on the application of HFEPR to transition metal coordination chemistry, in particular