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Multi-Dimensional Crystal Structures and Unique Solid-State Properties of Heterocyclic Thiazyl Radicals and Related Materials

โœ Scribed by Kunio Awaga; Toshiyuki Tanaka; Takahiro Shirai; Masato Fujimori; Yosuke Suzuki; Hirofumi Yoshikawa; Wataru Fujita


Publisher
John Wiley and Sons
Year
2006
Weight
8 KB
Volume
37
Category
Article
ISSN
0931-7597

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โœฆ Synopsis


Abstract

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Electrically conducting neutral radical crystals can be obtained by electrochemical oxidation of dicyano(phthalocyaninato)cobalt(III) anion, [Co(Pc)(CN) 2 ] ร€ . The electrolysis of the potassium salt in DMSO gives Co(Pc)(CN) 2 ร2DMSO. The solvent-free crystal can be obtained by electrolysis of K[Co(