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Multi-component analysis of concentrated solutions by flow-injection analysis with zone sampling and partial least-squares resolution

✍ Scribed by M. Blanco; J. Coello; H. Iturriaga; S. Maspoch; M. Redón; J. Riba


Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
483 KB
Volume
259
Category
Article
ISSN
0003-2670

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✦ Synopsis


The potential of a flow-mJechon-zone samphng system equtpped with a dmde-array spectrophotometnc detector for the simultaneous determmatlon of metal 1011s 111 mrxtures was studled Zone samplmg was accomphshed by usmg a uxnmerc~ally avadable, vanable-volume, dual-channel bypass mJectlon valve The mixed spectra were recorded at the maxlmum of the flow-mjectlon peaks and were resolved mto the mdwldual components by using a partial least-squares method The method was apphed to the detemunatlons of Cu(I1) and Z&I) m murtures with 4-(2-pyr~dylazo)resorcmol as reagent


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Multicomponent flow injection based anal
✍ O. Hernández; F. Jiménez; A.I. Jiménez; J.J. Arias; J. Havel 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 548 KB

Flow injection analysis @IA) with multiwavelength scanning of the FL4 peaks using a diode array detector (DAD) has been combined with a multivariate calibration approach applying the partial least squares (PLS) method for the data evaluation. In this way, various side effects like dilution of the re