Flow injection analysis @IA) with multiwavelength scanning of the FL4 peaks using a diode array detector (DAD) has been combined with a multivariate calibration approach applying the partial least squares (PLS) method for the data evaluation. In this way, various side effects like dilution of the re
Multi-component analysis of concentrated solutions by flow-injection analysis with zone sampling and partial least-squares resolution
✍ Scribed by M. Blanco; J. Coello; H. Iturriaga; S. Maspoch; M. Redón; J. Riba
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 483 KB
- Volume
- 259
- Category
- Article
- ISSN
- 0003-2670
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✦ Synopsis
The potential of a flow-mJechon-zone samphng system equtpped with a dmde-array spectrophotometnc detector for the simultaneous determmatlon of metal 1011s 111 mrxtures was studled Zone samplmg was accomphshed by usmg a uxnmerc~ally avadable, vanable-volume, dual-channel bypass mJectlon valve The mixed spectra were recorded at the maxlmum of the flow-mjectlon peaks and were resolved mto the mdwldual components by using a partial least-squares method The method was apphed to the detemunatlons of Cu(I1) and Z&I) m murtures with 4-(2-pyr~dylazo)resorcmol as reagent
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