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MS-TOF Study of the Formation of Thiolato-Bridged Rhodium Oligomers

✍ Scribed by Josée Boudreau; Jérôme Grenier-Desbiens; Frédéric-Georges Fontaine

Book ID
102829292
Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
814 KB
Volume
2010
Category
Article
ISSN
1434-1948

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✦ Synopsis

Rhodium / S ligands

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Study of the thermal evolution of the cy
Study of the thermal evolution of the cyclic-oligomer formation in a cyclic-oligomer-free PET
✍ V. Vermylen; P. Lodefier; J. Devaux; R. Legras; W. A. Mac Donald; R. Rozenberg; 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 162 KB 👁 2 views

A low percentage of cyclic oligomers can be found in poly(ethylene terephthalate) (PET) from its synthesis onward. In this article, a cyclic-oligomer-free PET (COFP) obtained by solvent extraction was used to study the thermodynamics of the re-formation of cyclics from the melt. The cyclic-oligomer