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Motions of CH2COOH and CH(COOH)2 radicals trapped in malonic acid single crystals determination of the 13C coupling tensors corresponding to the motionless radicals

✍ Scribed by L. Bonazzola; C. Hesse-Bezot; J. Roncin

Publisher: Elsevier Science
Year: 1975
Tongue: English
Weight: 532 KB
Volume: 9
Category: Article
ISSN: 0301-0104
DOI: 10.1016/0301-0104(75)80132-7

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13C hyperfine coupling and structure of

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✍ Anders Lund; Yuhei Shimoyama 📂 Article 📅 1976 🏛 Elsevier Science 🌐 English ⚖ 321 KB

Measurement of the 13C hyperfine coupling constant of -CHC12 in singe crystal CH2C& at 77 K leads to the Lonclusion that the radical converts between two equivalent pyramidal structures at a rate s@ifiuntly higher than 10' Hz. The anisotropy of the g-factor and the I H, 35C1 and 13C hyperfime coupli