Morphology Dependent Double Yielding in Injection Molded Polycarbonate/Polyethylene Blend

✍ Scribed by Zhong-Ming Li; Chen-Guang Huang; Wei Yang; Ming-Bo Yang; Rui Huang

• Publisher: John Wiley and Sons
• Year: 2004
• Tongue: English
• Weight: 394 KB
• Volume: 289
• Category: Article
• ISSN: 1438-7492
• DOI: 10.1002/mame.200400145

✦ Synopsis

Abstract

Summary: Polycarbonate (PC)/polyethylene (PE) blend was injection molded at different molding temperatures. The morphological observation by scanning electronic microscope (SEM) indicated that the sample molded at 190 °C contained only uniformly dispersed spherical PC particles. The samples molded at 230 and 275 °C had a typical skin‐core structure, and there were many injection‐induced PC fibers in the subskin. While the sample molded at 190 °C had the usual stress‐strain behavior, the samples obtained at 230 and 275 °C showed apparently double yielding behavior. It was suggested that the double yielding points were morphology‐dependent. The first one was the result of the yielding of PE at low strain, and the second one was caused by the yielding of the PC fibers. Moreover, it is the frictional force in the interfaces between PC and PE that transferred the stress to the PC fibers, hence giving rise to the reinforcement of PE by PC.

Stress‐strain curves of PC/PE blends injection molded at various temperatures showing first (I) and second (II) yielding points.

magnified imageStress‐strain curves of PC/PE blends injection molded at various temperatures showing first (I) and second (II) yielding points.