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Morphology and Tensile Strength Prediction of in situ Microfibrillar Poly(ethylene terephthalate)/Polyethylene Blends Fabricated via Slit-Die Extrusion-Hot Stretching-Quenching

✍ Scribed by Zhong-Ming Li; Wei Yang; Bang-Hu Xie; Kai-Zhi Shen; Rui Huang; Ming-Bo Yang


Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
260 KB
Volume
289
Category
Article
ISSN
1438-7492

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✦ Synopsis


Abstract

Summary: In situ microfibrillar poly(ethylene terephthalate) (PET)/polyethylene blends (MRB) were successfully fabricated by slit‐die extrusion‐hot stretching‐quenching. The morphology of this new material is mainly influenced by the composition and the hot stretching. Appropriate PET concentrations and a comparatively high hot stretching ratio could facilitate the fibrillation of PET domains during processing. The expression employed for prediction of the tensile strength for the microfibrillar blend was proved to be desirable. The prediction was, generally, in agreement with the experimental results, although the values of some parameters were approximated.

SEM micrograph of the cryofractured surface of the in situ microfibrillar PET/PE blend after injection molding.

imageSEM micrograph of the cryofractured surface of the in situ microfibrillar PET/PE blend after injection molding.


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✍ Zhong-Ming Li; Liang-Bin Li; Kai-Zhi Shen; Wei Yang; Rui Huang; Ming-Bo Yang 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 405 KB

## Abstract **Summary:** Isotactic poly(propylene) (iPP) transcrystallites are obtained in in situ microfibrillar polyethylene terephthalate (PET)/iPP blends during a slit extrusion‐hot stretching‐quenching process. Based on morphological information from X‐ray scattering and microscopy, three nucl