## Abstract The thermally initiated emulsion copolymerization of styrene (ST) and methyl methacrylate (MMA) was carried out in the absence of conventional initiators. The hydroperoxide (HPO) concentration in the monomers, sodium dodecyl sulfate (SDS), deionized water, and the formulation of those f
Morphological studies in thermally initiated emulsion (co)polymerization without conventional initiators
β Scribed by Yong-Zhong Du; Guang-Hui Ma; Hen-Mei Ni; Masatoshi Nagai; Shinzo Omi
- Publisher
- John Wiley and Sons
- Year
- 2002
- Tongue
- English
- Weight
- 701 KB
- Volume
- 84
- Category
- Article
- ISSN
- 0021-8995
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The influence of the initiator structure on the reaction process was investigated. In addition to the initiator concentration, its molar mass and the content of perester groups in the single molecule are determining factors that influence the course of reaction. Quantitative relationships are shown.
Ring opened metathesis polymerization was carried out on a number of cyclic olefins using Cl 2 (PCy 3 ) 2 Ru[CH(Ph)] and [( 6 -p-cymene)(PCy 3 )RuCl( C C CPh 2 )]OTf in dichloromethane and a range of ionic liquids. Microstructural parameters were determined from the 13 C NMR spectra recorded of the