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Morphological control and assembly of zinc oxide using a biotemplate

✍ Scribed by Melanie M. Tomczak; Maneesh K. Gupta; Lawrence F. Drummy; Sophie M. Rozenzhak; Rajesh R. Naik


Book ID
103999556
Publisher
Elsevier Science
Year
2009
Tongue
English
Weight
550 KB
Volume
5
Category
Article
ISSN
1742-7061

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✦ Synopsis


Zinc oxide is a wide band gap material that has significant applications in photovoltaics, piezoelectrics and optoelectronics. Traditionally, ZnO has been synthesized using high temperatures and harsh reaction conditions. Recently, benign reaction conditions have been used to synthesize ZnO using amine and citrate additives. In this study, peptide phage display was performed to identify a peptide, termed Z1, that binds to and directs the growth of ZnO hexagonal nanocrystals. By altering the concentration of Z1 peptide, the ZnO nanocrystal morphology can be tailored. Additionally, Z1 peptide was used to direct the growth of ZnO structures on free-standing silk films. The results presented here demonstrate the utility of peptides in controlling the structure and deposition of ZnO.


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## Abstract Nanoplates, flower‐like nanostructure of ZnO were successfully synthesized by employing ZnSO~4~Β·7H~2~O, NaOH as the starting materials at 120Β°C under hydrothermal condition. Keeping the same parameters, ZnO urchin shape was obtained by addition of vitamin C at 190Β°C. Characterizations w