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Montmorillonite-K10 Catalyzed Addition OF Trimethylsilylcyanide (TMSCN) to Aldehydes.

โœ Scribed by Somanathan, R.; Rivero, I. A.; Gama, Angeles; Ochoa, A.; Aguirre, G.


Book ID
120604836
Publisher
Taylor and Francis Group
Year
1998
Tongue
English
Weight
234 KB
Volume
28
Category
Article
ISSN
0039-7911

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Thiourea-catalyzed nucleophilic addition
โœ Tomotaka Okino; Yasutaka Hoashi; Yoshiji Takemoto ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 137 KB

The effect of hydrogen bonding between nitrones and urea derivatives in the nucleophilic addition reaction was examined. Thioureas bearing an electron-withdrawing group on an aromatic ring, behave like Lewis acid to promote the addition of TMSCN and ketene silyl acatals to various nitrones and aldeh