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Monte Carlo simulations of polymer degradations. 2. Degradations involving random chain scissions and volatilization of low molecular weight products

✍ Scribed by Guaita, Marino; Chiantore, Oscar; Luda, Maria Paola

Book ID: 121391412
Publisher: American Chemical Society
Year: 1991
Tongue: English
Weight: 582 KB
Volume: 24
Category: Article
ISSN: 0024-9297
DOI: 10.1021/ma00009a010

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Dependencies of PDI on monomer conversion (a = ([M] 0 -[M])/[M] 0 ) for systems with [M] 0 /[I] 0 = 10 2 , computed for various (shown in the Figure) values of (k tr / k p ) N ([M] 0 /[I] 0 ). Dotted lines: systems without disproportionation (Ref. [1] ), circles: systems with disproportionation.