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Monte Carlo simulation of mixing in Ca3Fe2Ge3O12–Ca4Ge4O12garnets and implications for the thermodynamic stability of pyrope–majorite solid solution

✍ Scribed by Victor L. Vinograd; Bjoern Winkler; Daniel J. Wilson; Andrew Putnis; Julian D. Gale


Publisher
Springer-Verlag
Year
2006
Tongue
English
Weight
346 KB
Volume
33
Category
Article
ISSN
0342-1791

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Solid Solutions Ca3Sn2+xSi(Ge)1-xGa2O12
✍ A. Rulmont; P. Tarte; B. Cartié; J. Choisnet 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 466 KB

Pure solid solutions \(\mathrm{Ca}_{3} \mathrm{Sn}_{2+x} \mathrm{Si}(\mathrm{Ge})_{1-x} \mathrm{Ga}_{2} \mathrm{O}_{12}\) with the garnet structure have been evidenced in the composition range \(0 \leq x \leq 0.95\). This implies that a part of the \(\mathrm{Sn}^{4+}\) cations (equal to \(x\) ) is l