Mononuclear Silylvinylidene Rhodium Complexes from Silylalkynes: The SiMe3 Migration as an Alternative to the [1,2]-H Shift

Molecular Structures of Mononuclear Rhod

Molecular Structures of Mononuclear Rhodium Complexes Containing the Polydentate Ligand Tri(1-cyclohepta-2,4,6-trienyl)phosphane, P(C7H7)3. Classification according to the 31P Chemical Shifts

✍ Max Herberhold; Wolfgang Milius; Stefan Eibl 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 German ⚖ 123 KB 👁 2 views

The olefinic phosphane P(C 7 H 7 ) 3 (5) behaves as a tetradentate tripod ligand in [RhCl{P(g 2 -C 7 H 7 ) 3 }] (6), using all 3 cyclohepta-2,4,6-trienyl substituents as g 2 -coordinating side-arms. Nucleophilic displacement of the one-electron chloro ligand by halides or pseudohalides to give [RhX{

Mononuclear Silylvinylidene Rhodium Complexes from Silylalkynes: The SiMe3 Migration as an Alternative to the [1,2]-H Shift

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