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Mononuclear Platinum(II) Complexes of a Bis(bidentate) Ligand Based on 1,3,4-Oxadiazole and Their Reactions with Copper(I) Salts

✍ Scribed by Marc-Etienne Moret; Peter Chen

Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
633 KB
Volume
2010
Category
Article
ISSN
1434-1948

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✦ Synopsis

Platinum / Copper / N ligands / Metal-metal interactions / Bridging ligands Reaction of the bis(bidentate) ligand 2,5-bis[2-(dimethylamino)phenyl]-1,3,4-oxadiazole (oxanMe) with the precursors trans-[PtMeCl(SMe 2 ) 2 ] and [(PhCN) 2 PtCl 2 ] afforded the mononuclear complexes [(oxanMe)Pt(Me)Cl] and [(oxanMe)-PtCl 2 ], respectively. [(oxanMe)PtMe 2 ] was observed in equilibrium with oxanMe, [Pt 2 Me 4 (µ-SMe 2 ) 2 ], and [PtMe 2 -(SMe 2 ) 2 ], but could not be isolated. Reaction of [(oxanMe)-

📜 SIMILAR VOLUMES

Probing the Dinucleating Behaviour of a
Probing the Dinucleating Behaviour of a Bis-Bidentate Ligand: Synthesis and Characterisation of Some Di- and Mononuclear Cobalt(II), Nickel(II), Copper(II) and Zinc(II) Complexes of 3,5-Di(2-pyridyl)-4-(1H-pyrrol-1-yl)-4H-1,2,4-triazole
✍ Marco H. Klingele; Peter D. W. Boyd; Boujemaa Moubaraki; Keith S. Murray; Sally 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 292 KB

## Abstract As a probe of the dinucleating ability of the known but little studied bis‐bidentate ligand 3,5‐di(2‐pyridyl)‐4‐(1__H__‐pyrrol‐1‐yl)‐4__H__‐1,2,4‐triazole (pldpt) its reactivity towards MX~2~·6H~2~O (M = Co^II^, Ni^II^ and Zn^II^; X = ClO~4~^–^ and BF~4~^–^) as well as Cu(ClO~4~)~2~·6H~