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Mononuclear [Ni II (L)(P-( o -C 6 H 4 S) 2 ( o -C 6 H 4 SH))] 0/1- (L = Thiolate, Selenolate, PPh 3 , and Cl) Complexes with Intramolecular [Ni···S···H···S]/[Ni···H···S] Interactions Modulated by the Coordinated Ligand L: Relevance to the [NiFe] Hydrogenases

✍ Scribed by Chen, Chien-Hong; Lee, Gene-Hsiang; Liaw, Wen-Feng


Book ID
126440248
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
296 KB
Volume
45
Category
Article
ISSN
0020-1669

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The nickel complex 2 Ni shows reactivity about 10 3 times greater than that of the cobalt analogue 2 Co . The oxidation ability of the M III (m-O) 2 M III core should be affected by the hindered Tp R ligand system, which can stabilize the 2 oxidation state of the metal centers.