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Mononuclear heterocyclic rearrangements involving a sulphur atom: conversion of 1,2,4-oxadiazoles into 1,2,4-thiadiazoles

✍ Scribed by Ruccia, M.; Vivona, N.; Cusmano, G.


Book ID
120832452
Publisher
The Royal Society of Chemistry
Year
1974
Tongue
English
Weight
94 KB
Volume
9
Category
Article
ISSN
0022-4936

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Photoinduced molecular rearrangements. T
✍ NicolΓ² Vivona; Silvestre Buscemi; Stefano Asta; Tullio Caronna πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 French βš– 417 KB

The photochemistry of some 1,2,4-oxadiazoles in the presence of sulphur nucleophiles has been investigated. Irradiation of the 5-amino-3-phenyl-and 3,5-diphenyl-l,2,4-oxadiazole at X = 254 nm in methanol in the presence of sodium hydrogen sulphide or thiols gave a photo-induced redox reaction at the