Monomeric Magnesium and Calcium Complexes Containing the Bidentate, Dianionic 1,2-Bis[(2,6-diisopropylphenyl)imino]acenaphthene Ligand
✍ Scribed by Igor L. Fedushkin; Alexandra A. Skatova; Valentina A. Chudakova; Georgy K. Fukin; Sebastian Dechert; Herbert Schumann
- Publisher
- John Wiley and Sons
- Year
- 2003
- Tongue
- English
- Weight
- 246 KB
- Volume
- 2003
- Category
- Article
- ISSN
- 1434-1948
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## Abstract The ligand __N,N′__‐bis(6‐methyl‐2‐pyridylmethyl)‐__N,N′__‐bis(2‐pyridylmethyl)ethane‐1,2‐diamine (L~6~^2^2M) has allowed to prepare the new Fe^II^ complex [(L~6~^2^2M)FeCl~2~] (1), and to compare its structural and spectroscopic characteristics with [(L~6~^2^2M)FeCl]PF~6~ (2). The mole
## Abstract The complex __trans__‐[RuCl~2~{κ^2^‐__P__,__P__‐(__S__)‐peap}~2~] (1) has been stereoselectively prepared by the treatment of a stoichiometric mixture of complex [RuCl~2~(DMSO)~4~] (DMSO = dimethyl sulfoxide) and (__S__)‐peap [(__S__)‐peap = (−)‐__N__,__N__‐bis(diphenylphosphanyl)‐(__S_