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Monomeric and Dimeric Iron(III) Complexes of 5-Hydroxy-10,15,20-triphenylporphyrin: Formation of Cyano and Pyridine Complexes of (5-Oxo-10,15,20-triphenylphlorin)iron

✍ Scribed by Jacek Wojaczyński; Marcin Stępień; Lechosław Latos-Grażyński


Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
281 KB
Volume
2002
Category
Article
ISSN
1434-1948

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✍ Tapan Kumar Saha; Subarna Karmaker; Keietsu Tamagake 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 279 KB

High-valent oxo-iron(IV) species are commonly proposed as the key intermediates in the catalytic mechanisms of iron enzymes. Water-soluble iron(III) tetrakis-5,10,15,20-(N-methyl-4-pyridyl)porphyrin (Fe(III)TMPyP) has been used as a model of heme-enzyme to catalyse the hydrogen peroxide (H 2 O 2 ) o