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Monomer Reactivity and Steric Factors affecting the Synthesis of Aromatic Polyamides

✍ Scribed by Munoz, D. M.; Lozano, A. E.; De La Campa, J. G.; De Abajo, J.

Book ID
121654821
Publisher
SAGE Publications
Year
2007
Tongue
English
Weight
229 KB
Volume
19
Category
Article
ISSN
0954-0083

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Quantum semiempirical study on the react
Quantum semiempirical study on the reactivity of silylated diamines in the synthesis of aromatic polyamides
✍ Angel E. Lozano; Javier de Abajo; JosΓ© G. De la Campa πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 638 KB

The reasons for the reactivity increase toward acyl chlorides caused in aromatic amines by silylation are studied by quantum semiempirical and ub initio methods. Silylated amino groups adopt an sp2 planar geometry, in contrast to that observed in the unsilylated series, where a partially pyramidal s