Monodentate Chiral Spiro Phosphoramidites: Efficient Ligands for Rhodium-Catalyzed Enantioselective Hydrogenation of Enamides
β Scribed by Ai-Guo Hu; Yu Fu; Jian-Hua Xie; Hai Zhou; Li-Xin Wang; Qi-Lin Zhou
- Publisher
- John Wiley and Sons
- Year
- 2002
- Tongue
- English
- Weight
- 87 KB
- Volume
- 114
- Category
- Article
- ISSN
- 0044-8249
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## Abstract A new class of lowβcost and easyβtoβprepare monodentate phosphoramidite ligands (CydamPhos) has been developed from readily accessible and cheap __trans__β1,2βdiaminocyclohexane as starting material through a threeβstep transformation. This type of ligands exhibited excellent enantiosel
We thank the European Commission [RTN Network (R)Evolutionary Catalysis MRTN-CT-2006-035866] for financial support. L. Pignataro thanks Milan University for a postdoctoral fellowship ("Assegno di ricerca"). HRMS spectra were performed at CIGA (Milan University). We are grateful to Dr. Laura Belvisi
We thank the European Commission [RTN Network (R)Evolutionary Catalysis MRTN-CT-2006-035866] for financial support. L. Pignataro thanks Milan University for a postdoctoral fellowship ("Assegno di ricerca"). HRMS spectra were performed at CIGA (Milan University). We are grateful to Dr. Laura Belvisi