Mono-, di- and tetranuclear rhodium(I) complexes of morpholine andN-methylpiperazine functionalized cyclodiphosph(III)azanes,cis-[(tBuN-μ)2(PNC4H8X)2] (X = O, NMe)

Mono-, Bi-, Tri- and Tetranuclear Pallad

Mono-, Bi-, Tri- and Tetranuclear Palladium(II), Copper(I), and Gold(I) Complexes of Morpholine- and N-Methylpiperazine-Functionalized Cyclodiphosph(III)azans, cis-[(tBuN-μ)2(PNC4H8X)2] (X = O, NMe)

✍ Maravanji S. Balakrishna; Devarajan Suresh; Joel T. Mague 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 732 KB

Bis(amido)cyclodiphosphazanes, cis- [(tBuN-µ) (2) and cis- [(tBuN-µ) 2 (PNC 4 H 8 NMe) 2 ] (3) were synthesized by treating the corresponding amines with cis-[ClP(tBuN-µ) 2 -PCl] (1). The stoichiometric reactions of 2 or 3 with elemental sulfur and selenium afforded the bis-chalcogenides, cis-[(tBu