Mono- and multimolecular nucleation in polymer crystallization
โ Scribed by R. S. Zurabyan; V. G. Baranov; S. Ya. Frenkel'
- Publisher
- Springer US
- Year
- 1975
- Tongue
- English
- Weight
- 223 KB
- Volume
- 10
- Category
- Article
- ISSN
- 1573-8922
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๐ SIMILAR VOLUMES
## Abstract Primary nucleation is in general heterogeneous in polymer crystallization. In unseeded polymers, the crystallization originates from a very small concentration (<0.1 percent) of unknown submicroscopic heterogeneous nuclei. Only in three cases have the nucleation mechanisms been identifi
We report dynamic Monte Carlo simulations of crystal nucleation in polymer bulk phase segregated from solutions. We found that poorer solvent enhances crystal nucleation in the concentrated phase of polymers. In addition, when the solvent becomes poor enough, crystal nucleation prefers to occur at t