A novel electroactive material for ascorbic acid (AA) determination was successfully prepared by plating/potential cycling method. The cobalt film was first deposited on the surface of glassy carbon electrode (GCE) in CoSO 4 solution by potential cycling, and then a cobalt film on the surface of GCE
Mono- and multilayer formation studies of cobalt on glassy carbon electrode
โ Scribed by S. Jaya; T.Prasada Rao; G.Prabhakara Rao
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 401 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0013-4686
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โฆ Synopsis
This paper reports the results of the study of mono-and multilayer formation of cobalt on glassy carbon electrode as a function of sweep rate, cathodic potential limit of the triangular scan and concentration of cobalt. Cyclic and linear potential sweep techniques were employed in carrying out these studies. The multilayer formation of cobalt occurs by 3-D nucleation-growth processes only at concentration 3 10e3 M ofcobalt. On the other hand, the monolayer stripping pattern shows two peaks. The characterization of these peaks by the theoretical models reported in literature revealed that the monolayer formation of cobalt occurs by nucleation-growth and des-ad kinetic processes.
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