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Mono- and Diadducts and Bicyclic Adducts in Reactions of 2,3-Dicyano-1-ethylpyrazinium Cation with C- and O-Nucleophiles.

✍ Scribed by P. A. Slepukhin; G. L. Rusinov; V. N. Charushin; V. I. Filyakova; N. S. Karpenko; D. B. Krivolapov; I. A. Litvinov

Publisher: John Wiley and Sons
Year: 2005
Weight: 29 KB
Volume: 36
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200509159

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✦ Synopsis

Abstract

For Abstract see ChemInform Abstract in Full Text.

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## Abstract magnified image Described herein is the development of a palladium(II)‐catalyzed two‐ or three‐component reaction of 2‐(1‐alkynyl)‐2‐alken‐1‐ones with nucleophiles and allylic chlorides. Various types of nucleophiles such as __O‐__, __N‐__, __C__‐based nucleophiles and olefin‐tethered