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Mono and Bimetallic Complexes of Molybdenum(ii) and Tungsten(ii) Containing 4,4′-Diphenylenecarbonitrile

✍ Scribed by Baker, Paul K.; Veale, Patrick L.


Book ID
126599427
Publisher
Taylor and Francis Group
Year
2003
Tongue
English
Weight
164 KB
Volume
56
Category
Article
ISSN
0095-8972

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Seven-coordinate complexes of molybdenum
✍ Paul K. Baker; Marit van Kampen; Christina Roos; Julia Spaeth 📂 Article 📅 1994 🏛 Springer 🌐 English ⚖ 352 KB

Equimolar quantities of [MI2(CO)3(NCMe)2 ] (M = Mo or W) and C3H4N2 (pyrazole) react in CH2C12 at room temperature to give the iodo-bridged dimers [M(#-I)(CO)3(C:~H~N2)]2 (I) and (2). Two equivalents of C3H4N 2 react with [MIz(CO)a(NCMe)2] (M = Mo or W) to give the bis(pyrazole) complexes [MIz(CO)3(