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Mono- and bimetallic chromium(III) complexes containing 2,3,5,6-tetrakis-(α-pyridyl)pyrazine as a tridentate ligand: synthesis and spectroscopic characterization

✍ Scribed by Rodrigo S. Bitzer; Carlos A. L. Filgueiras; José Guilherme S. Lopes; Paulo Sérgio Santos; Marcelo H. Herbst


Book ID
106547063
Publisher
Springer
Year
2005
Tongue
English
Weight
275 KB
Volume
30
Category
Article
ISSN
0340-4285

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Synthesis of a polymetallic Pt, Sn compl
✍ Wagner M. Teles; Nivaldo L. Speziali; Carlos A.L. Filgueiras 📂 Article 📅 2000 🏛 Elsevier Science 🌐 English ⚖ 142 KB

Reaction between 2,3,5,6-tetrakis(a-pyridyl)pyrazine (TPP) and the dimer , in which TPP behaves as a bis(bidentate) ligand between the two Pt atoms of the cation. Insertion of SnCl 2 into the Pt-Cl bonds of this compound led to an unusual rearranged product, (2), with a rare example of a pentacoor