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[Mo{N2C(S)SC2H5}{NH2NC(S)SC2H5}{(CH3)2NCS2}2] — ein schwefelreicher, siebenfach koordinierter Diazenido-hydrazido(1 –)-molybdän-Komplex

✍ Scribed by Prof. Dr. Rainer Mattes; Heinz Scholand

Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
194 KB
Volume
95
Category
Article
ISSN
0044-8249

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📜 SIMILAR VOLUMES

[Mo{N2C(S)SC2H5}{NH2NC(S)SC2H5}{(CH3)2NC
[Mo{N2C(S)SC2H5}{NH2NC(S)SC2H5}{(CH3)2NCS2}2]-A Sulfur-Rich Haptacoordinated Diazenidohydrazido(1–) molybdenum Complex
✍ Prof. Dr. Rainer Mattes; Heinz Scholand 📂 Article 📅 1983 🏛 John Wiley and Sons 🌐 English ⚖ 231 KB 👁 1 views

In competition experiments with heptanal/diethyl ketone (1 : 1) it could be shown that 1, 3b and 4b olefinate aldehyde groups without the keto groups being attacked. Presumably the carbonyl olefinations proceed as formulated for lc7l. The postulated product 2a, however, has so far evaded detection.