Molybdenum Complexes with Sterically Demanding Cycloheptatrienyl Ligands
✍ Scribed by Dressel, Bernd; Fröhlich, Roland; Kunz, Doris; Tamm, Matthias; Bannenberg, Thomas
- Book ID
- 115493300
- Publisher
- American Chemical Society
- Year
- 2001
- Tongue
- English
- Weight
- 144 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0276-7333
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📜 SIMILAR VOLUMES
## Abstract Deprotonation of Ap\*H {Ap\*H = (2,6‐diisopropylphenyl)‐[6‐(2,4,6‐triisopropylphenyl)pyridin‐2‐yl]amine} and Ap'H {Ap'H = (2,6‐diisopropylphenyl)‐[6‐(2,6‐dimethylphenyl)pyridin‐2‐yl]amine} using KH leads to polymeric [Ap\*K]__~n~__ and [Ap'K]__~n~__ which undergo clean salt metathesis r
The synthesis of P-functionalized molybdenum chelate complexes incorporating the linked cycloheptatrienylphosphane ligand [2-(diphenylphosphanyl)phenyl]cycloheptatrienyl, o-Ph 2 P-C 6 H 4 -C 7 H 6 , is described. The air-stable ligand precursor [2-(cyclohepta-2,4,6-trienyl)phenyl]diphenylphosphane (