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Molybdenum-catalysed allylic amination of alkenes by arylamine?ButOOH

✍ Scribed by Srivastava, Radhey S.; Nicholas, Kenneth M.

Book ID
118028083
Publisher
Royal Society of Chemistry
Year
1996
Tongue
English
Weight
244 KB
Volume
20
Category
Article
ISSN
1359-7345

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Manganese-porphyrins and particularly Mn(TPP)(C104) were found to be much better catalysts than iron-porphyrins for allylic N-tosylamination of alkenes by tosyliminoiodobenzene. With the former catalysts, cyclohexene was selectively transformed into 3-tosylaminocyclohexene with yields up to 70% and