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Molecule-Based Magnetic Materials

โœ Scribed by Eugenio Coronado; Fernando Palacio; Jaume Veciana


Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
93 KB
Volume
42
Category
Article
ISSN
0044-8249

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Studies of a Nickel-Based Single-Molecul
โœ Hanspeter Andres; Reto Basler; Alexander J. Blake; Cyril Cadiou; Gregory Chabous ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 223 KB ๐Ÿ‘ 2 views

A cyclic complex [Ni(12)(chp)(12)(O(2)CMe)(12)(thf)(6)(H(2)O)(6)] (1) has been synthesised and studied (chp=6-chloro-2-pyridonate). Complex 1 exhibits ferromagnetic exchange between the S=1 centres, giving an S=12 spin ground state. Detailed studies demonstrate that it is a single-molecule magnet wi