Molecular weight distribution of the polyacrylonitrile moiety of starch-polyacrylonitrile graft copolymers
✍ Scribed by Gugliemelli, L. A. ;Weaver, M. O. ;Russell, C. R. ;Rist, C. E.
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1971
- Tongue
- English
- Weight
- 217 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0449-2986
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The Mn3+ initiation system has been used to prepare starch-g-polyacrylonitrile copolymers. Both granular native starch and water-swollen gelatinized starch have been used as substrate. Conversion of monomer, graiting ratio, and percent add-on tend to increase with increasing amounts of monomer charg
## Abstract The effect of concentration, reactant ratios, temperature, and starch pretreatment on grafting of acrylonitrile onto starch were studied. Grafting was efficient at high concentrations (8–12% starch) when granular starch was used. The molecular weights for grafted polyacrylonitrile (PAN)