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Molecular Weight Development in Free-Radical Polymerization with Polyfunctional Chain-Transfer Agents, 1. Equal Reactivity Model

✍ Scribed by Hidetaka Tobita; Mizue Hayashi

Publisher: John Wiley and Sons
Year: 2001
Tongue: English
Weight: 144 KB
Volume: 10
Category: Article
ISSN: 1022-1344
DOI: 10.1002/1521-3919(20010701)10:6<573::aid-mats573>3.0.co;2-8

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Free-radical polymerization of styrene was carried out in the presence of chain transfer agents (CTAs) with functionality, f ϭ 1-4. The size exclusion chromatography (SEC) with an ultraviolet absorption detector (UV) was used to measure the molecular weight distribution (MWD). A Monte Carlo simulati