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Molecular structures of vinylarsine, vinyldichloroarsine and arsine studied by gas-phase electron diffraction and quantum chemical calculations

✍ Scribed by Robert Noble-Eddy; Sarah L. Masters; David W.H. Rankin; Heather E. Robertson; Jean-Claude Guillemin


Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
661 KB
Volume
978
Category
Article
ISSN
0022-2860

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Molecular structure of tris(cyclopropyls
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The molecular structure and conformation of tris(cyclopropylsilyl)amine (TCPSA) has been studied by means of gas-phase electron diffraction at 338 K and quantum-chemical calculations. A total of 12 relatively stable conformations of TCPSA molecule were considered. According to the experimental resul