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Molecular Structures of Tri- O-acetyl-D-glucal and Ethyl-4, 6-di- O-acetyl-2, 3-dideoxy-α-D-erythro-2-hexenopyranoside

✍ Scribed by Prof. Dr. Wolfgang Voelter; Dipl.-Chem. Wolfram Fuchs; Dr. John J. Stezowski; Petra Schott-Kollat


Publisher
John Wiley and Sons
Year
1981
Tongue
English
Weight
217 KB
Volume
20
Category
Article
ISSN
0044-8249

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NMR study of methyl 3,4,6-tri-O-acetyl-2
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Five derivatives of methyl 3,4,6-triacetyl-2-deoxy-(3@-dialkylureido)-b-D-glucopyranoside were studied by 1H and 13C, NMR spectroscopy in solutions and by 13C NMR spectroscopy in the solid state. Sterically CDCl 3 crowded substituents such as n-hexyl and cylcohexyl change the chemical shifts of H-1,