Molecular structures of complexes of rare-earth metals with benzo-12-crown-4
โ Scribed by S. V. Lindeman; Yu. T. Struchkov; Z. M. Alibaeva; N. I. Snezhko; L. I. Martynenko; N. I. Pechurova
- Publisher
- Springer Netherlands
- Year
- 1991
- Tongue
- English
- Weight
- 606 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0923-0750
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Novel molecular metal salts comprising an organic donor 2,5-bis(1, 3-dithiol-2-ylidene)-1,3,4,6-tetrathiapentalene (BDT-TTP) and lanthanide nitrato complex anions [M(NO 3 ) y ] ร(yร3) were synthesized as the composition (BDT-TTP) x [M(NO 3 ) y ]. Attempts on X-ray crystal structure analyses gave ris
## Abstract For Abstract see ChemInform Abstract in Full Text.
The lanthanide nitrate complexes with 13-crown-4(13-C-4) have been prepared in AcOEt. These new complexes with the general formula Ln(N03),.(13-C-4) (Ln = La-Nd, Sm-Lu) have been characterized by means of elemental analysis, IR and 'H-NMR spectra, conductivity measurements, and TG-DTA techniques. Th