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Molecular structures of 4,13-diaza-18-crown-6 derivatives having glycyl-glycine sidearms: two potassium iodide complexes

✍ Scribed by Banita D White; Frank R Fronczek; Richard D Gandour; George W Gokel

Book ID: 104227167
Publisher: Elsevier Science
Year: 1987
Tongue: French
Weight: 195 KB
Volume: 28
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)95412-1

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✦ Synopsis

Solid state structures are presented for two crystalline K+ complexes of &,N'-bis(methy1 glycidylglycidino)-4,13-diaza-18-crown-6.

The two different complexzco-crystallize and both structures are fully resolved. The sidearm-K+ interactions differ in each but in both cases the proximal (amide) carbonyl participates in cation binding while the distal (ester) carbonyl does not.

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