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Molecular structure of the C70 fullerene

✍ Scribed by Alexander V. Nikolaev; T.John S. Dennis; Kosmas Prassides; Alan K. Soper

Publisher: Elsevier Science
Year: 1994
Tongue: English
Weight: 454 KB
Volume: 223
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(94)00432-3

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✦ Synopsis

The molecular structure of C,e has been studied between 20 and 300 K using high-Q pulsed powder neutron difYraction of solid (&. The intra-and inter-molecular pair correlation functions were decoupled, allowing accurate determination of the intramolecular structure of CT,,. The C-C bond lengths range between R 1.38 and 1.48 A with no evidence of pinching in the equatorial region. There is essentially no change in the intermolecular structure on cooling, in contrast to the severe changes in the intermolecular pair correlation function that accompany orientational ordering.

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