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Molecular structure of stable nitroxyl radicals of imidazoline with gem-dialkoxy group at the α-carbon atom of the radical center

✍ Scribed by Yu. V. Gatilov; I. Yu. Bagryanskaya; I. A. Grigor'ev; I. A. Kirilyuk; L. B. Volodarskii


Publisher
SP MAIK Nauka/Interperiodica
Year
1992
Tongue
English
Weight
361 KB
Volume
33
Category
Article
ISSN
0022-4766

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Route to stable nitroxides with alkoxy g
✍ I.A. Grigor'ev; L.B. Volodarsky; V.F. Starichenko; G.I. Shchukin; I.A. Kirilyuk 📂 Article 📅 1985 🏛 Elsevier Science 🌐 French ⚖ 242 KB

Summaq: Oxidation of l-hydroxy-5,5-dimethyl-3\_imidazoline-3-oxides containing one or two hydrogen atoms in position 2 of the heterocycle with lead dioxide in alcohol leads to stable nitroxides with alkoxy groups at d-carbon, the derivatives of 2-and +imidazolines, via the intermediate formation of