Molecular structure of monomeric manganese (II) bromide with evidence on the structure of the dimer from electron diffraction

✍ Scribed by Magdolna Hargittai; István Hargittai; János Tremmel

• Publisher: Elsevier Science
• Year: 1981
• Tongue: English
• Weight: 286 KB
• Volume: 83
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(81)80321-1

✦ Synopsis

Received 8 June 1981; m final form 18 June 1981 h electron d&action investigation (at 608°C) determined rg(Mn-Br)= 2.344 + 0.006 A in MnF&. Assmnkg a Linear equilibrium c.o&igurat~on, ;he observled viir+onal amplitudes and shrinkage effect &owed estimation of the vibrational. frequencies. The dimer has a four-membered ring and a bridging bond longer than the bond of the monomer by 0.23 A.