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Molecular structure of 3-(3-oxo-bicyclo[2.2.1]hept-5-en-2-yl)-oxirane-2-carboxylic acid methyl ester

✍ Scribed by René de Gelder; Twan van Enckevort; J. M. M. Smits; Paul T. Beurskens; Jie Zhu; A. J. H. Klunder


Publisher
Springer
Year
1996
Tongue
English
Weight
220 KB
Volume
26
Category
Article
ISSN
1572-8854

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Diels-Alder reaction of furan with methy
✍ Jacques Leroy 📂 Article 📅 1992 🏛 Elsevier Science 🌐 French ⚖ 301 KB

Abs&cC The two epimers of methyl 3-oxo-7-oxabicyclo[2.2.l]hept-S-en-2-carboxylate have been prepared from furan and methyl 3-bromopropiolate as a melhoxycarbonylketcne equivalent. The final step required hydrolysis of acetals by Nafion-H. 7-Oxabicyclo[2.2.l]hept-5-en-2-yl derivatives, in an opticall