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Molecular Structure and Rubber-Like Elasticity. II. The Stereochemistry of Chain Polymers

✍ Scribed by Bunn, C. W.


Book ID
120133359
Publisher
The Royal Society
Year
1942
Tongue
English
Weight
637 KB
Volume
180
Category
Article
ISSN
0962-8444

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Studies have been made of the crystal and molecular structure of isotactic poly-5-methyl-1hexene, poly-(S)-5-methyl-l-heptene and poly-(S), (R)-5-methyl-l-heptene, using X-ray diffraction spectra of drawn fibres. The unit cell parameters are: ra = 17-62 A; b = 10.17 A; c = 6.33 .& (fibre axis) poly-