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Molecular solvent models of electrical double layers

✍ Scribed by G.M. Torrie; G.N. Patey


Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
869 KB
Volume
36
Category
Article
ISSN
0013-4686

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✦ Synopsis


This

paper summarizes some recent work directed towards the construction of a wholly molecular theory of the solution side of an electrical double layer using modem liquid state theory. The influence of surface charge on the solvent restructuring near the surface and the consequences of this for the ionic distributions in the double layer are discussed and related to the role of the continuum solvent description embodied in Gouy-Chapman theory.


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## ment in the computing facilities makes numerical solution of The unsteady-state electrical potential and the concentrations a complicated problem feasible, and approximate analytical of ions between two identical, negatively-charged particles imsolutions to PBE becomes convenient in the estimat