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Molecular Simulation of Disjoining-Pressure Isotherms for Free Aqueous Thin Films

✍ Scribed by Bhatt, Divesh; Newman, John; Radke, C. J.

Book ID
127023450
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
117 KB
Volume
107
Category
Article
ISSN
0022-3654

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A theory is presented to quantify the electrostatic forces in thin aqueous electrolyte films between two charge regulating surfaces. The Poisson-Boltzmann equation, as modified by Gur et al. (J. Colloid Interface Sci. 64, 326 (1978)) to include the effects of hydration free energy of ions, is numeri