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Molecular Simulation of Adsorption and Diffusion of Hydrogen in Metal−Organic Frameworks

✍ Scribed by Yang, Qingyuan; Zhong, Chongli

Book ID
120066637
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
161 KB
Volume
109
Category
Article
ISSN
0022-3654

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✍ Prof. Carlos O. Areán; Dr. Sachin Chavan; Carlos P. Cabello; Prof. Edoardo Garro 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 202 KB

## Abstract __Interaction between adsorbed hydrogen and the coordinatively unsaturated Mg^2+^ and Co^2+^ cationic centres in Mg‐MOF‐74 and Co‐MOF‐74, respectively, was studied by means of variable‐temperature infrared (VTIR) spectroscopy. Perturbation of the H~2~ molecule by the cationic adsorbing