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Molecular-sieve selectivity of narrow-pore zeolites in the cracking of hydrocarbons

โœ Scribed by L.N. Malashevich; A.V. Pis'mennaya

Book ID
116042702
Publisher
Elsevier Science
Year
1989
Weight
333 KB
Volume
29
Category
Article
ISSN
0031-6458

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Para-selective fries rearrangement of ph
Para-selective fries rearrangement of phenyl acetate in the presence of zeolite molecular sieves
โœ Colin S. Cundy; Raymond Higgins; Sarah A.M. Kibby; Barrie M. Lowe; R. Michael Pa ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 226 KB

The Fries rearrangement of phenyl acetate is catalysed by acidic zeolites such as H-Nu-2 and H-ZSM-5, with selectivities of 2-6:l in favout of para-substituted products. The Fries rearrangement of phenyl esters affords a mixture of o-and phydroxyphenylketones, together with phenol as a hydrolysis p