Molecular shape and crystal packing analysis of 11,11-disubstituted 1,6-methano[10]annulenes
β Scribed by R. Bianchi; A. Gavezzotti; M. Simonetta
- Book ID
- 119116575
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- English
- Weight
- 693 KB
- Volume
- 135
- Category
- Article
- ISSN
- 0166-1280
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π SIMILAR VOLUMES
In the previous paper (1) we have described a two-step synthesis of 1,6-methanaCl0lannulen-1 l-one from tropone. This compound, having the p-orbital of the carbonyl group .approximately perpendicular to the peripheral IOn-electron system, failed to exhibit appreciable n-n interaction between them. W
## Abstract The title compounds have been isolated and their structures determined by Xβray crystallography. Their relative stability is discussed in terms of theory and experiment. The __endo__βadduct is the thermodynamically more stable one.