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Molecular relaxation processes in dimethyldichlorosilane studied by vibrational spectroscopy

✍ Scribed by I. Bratu; Rodica Grecu; T. Iliescu

Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
283 KB
Volume
349
Category
Article
ISSN
0022-2860

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## Abstract Rotational and vibrational relaxation of pure liquid dimethyldichlorosilane (DMDCS) at temperatures of 279, 293, 308 and 323 K and in carbon tetrachloride, dioxane, chloroform and cyclohexane solutions at 293 K were studied by Raman band shape analysis. The activation energy for molecul

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The O-H fundamental band profiles of several alcohols in various solvents have been studied by the correlation function technique. It was found that the rotational contribution to the O-H band shape is not significant for these molecules except for methanol. The denendence of the vibrational correla