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Molecular Recognition of Carbonyl Compounds Using Aluminum Tris(2,6-diphenylphenoxide) (ATPH): New Regio- and Stereoselective Alkylation of α,β-Unsaturated Carbonyl Compounds

✍ Scribed by Saito, Susumu; Shiozawa, Masahito; Nagahara, Takashi; Nakadai, Masakazu; Yamamoto, Hisashi

Book ID
127391511
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
167 KB
Volume
122
Category
Article
ISSN
0002-7863

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ChemInform Abstract: Molecular Recogniti
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✍ Susumu Saito; Masahito Shiozawa; Takashi Nagahara; Masakazu Nakadai; Hisashi Yam 📂 Article 📅 2000 🏛 John Wiley and Sons ⚖ 37 KB 👁 2 views

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ChemInform Abstract: A New Synthetic Rou
ChemInform Abstract: A New Synthetic Route to Allylsilanes: The Reaction of Silyllithium Reagents with Aromatic Carbonyl Compounds and Aluminum Tris(2,6- diphenylphenoxide) (ATPH).
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Tris(2,6-diphenylphenoxide) (ATPH). -1,6-Addition of silyllithium reagents to aromatic carbonyl compound ATPH complex and following enolate capture with an appropriate electrophilic reagent leads to functionalized allylsilanes shown in the scheme. In the reaction of (I), aromatic silylated products