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Molecular rearrangements, part 33, photolysis and thermolysis of arylnitramines

โœ Scribed by M.Z.A. Badr


Book ID
104063007
Publisher
Elsevier Science
Year
2004
Tongue
English
Weight
116 KB
Volume
162
Category
Article
ISSN
1010-6030

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## Abstract 1โ€(Alkylthio)cyclopropyl azides โ€ readily accessible from the corresponding chlorides and bromides โ€ are smoothly decomposed at 70ยฐC with nitrogen evolution. The main process is a ring enlargement to 2โ€(alkylthio)azetines **2**, accompanied by cleavage to thiocyanate and alkene. Reactio